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Dressed local mode Hamiltonians for CH stretch vibrations

✍ Scribed by Sibert, Edwin L.

Book ID
125805234
Publisher
Taylor and Francis Group
Year
2013
Tongue
English
Weight
188 KB
Volume
111
Category
Article
ISSN
0026-8976

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πŸ“œ SIMILAR VOLUMES

Effective rotational Hamiltonian of the
Effective rotational Hamiltonian of the local mode vibrational states
✍ Qing-shi Zhu πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 English βš– 384 KB

The effective rotational Hamiltonians of the local mode states are derived for XY,, XY, and XY4 molecules by averaging the vibration-rotation Hamiltonians using the corresponding local mode vibrational wavefunctions. The results indicate that in a local mode vibrational state the molecular symmetry

Local mode and normal mode interpretatio
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✍ J.L. Duncan; I.M. Mills πŸ“‚ Article πŸ“… 1988 πŸ› Elsevier Science 🌐 English βš– 463 KB

The =CHI and =CD2 stretching vibrational overtones of H&-CD2 have been studied up to V= 6 and V= 3, respectively. We report their interpretation in terms of a transition from normal to local modes, involving Fermi resonance with the C-C stretching and CHz scissoring vibrations. We discuss the altern

Vibrationβ€”rotation Hamiltonian of tetrah
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✍ Mark S. Child; Qingshi Zhu πŸ“‚ Article πŸ“… 1991 πŸ› Elsevier Science 🌐 English βš– 231 KB

The stretching vibration-rotation Hamiltonian of tetrahedral molecules is derived in the local-mode model. The result shows that the effective rotational Hamiltonian of a local-mode state gives rise to symmetric-top rotational energy levels, which are quantitatively in good agreement with experiment