Local-mode to normal-mode hamiltonian transformation for X -H stretchings
β Scribed by Guido Della Valle, Raffaele
- Book ID
- 121501579
- Publisher
- Taylor and Francis Group
- Year
- 1988
- Tongue
- English
- Weight
- 634 KB
- Volume
- 63
- Category
- Article
- ISSN
- 0026-8976
No coin nor oath required. For personal study only.
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The high-resolution FTIR spectrum of the HDSe molecule in the presence of H 2 Se and D 2 Se was recorded on 80 Se monoisotopic and natural samples in the 1500 -2900 cm Οͺ1 region and theoretically analyzed in the regions of the stretching fundamental bands 1 and 3 near 1692 and 2351 cm Οͺ1 , respectiv
We present a simple, analytic model for the normal and local mode behavior of the stretching vibrations in AB, molecules. Starting with a zeroth-order description ofdegenerate, harmonic normal modes, we introduce a quartic perturbation and employ first-order secular perturbation theory to obtain a