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Dramatic Effect of Heteroatom Backbone Substituents on the Ethylene Polymerization Behavior of Bis(imino)pyridine Iron Catalysts

✍ Scribed by Smit, Theo M.; Tomov, Atanas K.; Gibson, Vernon C.; White, Andrew J. P.; Williams, David J.

Book ID: 115485290
Publisher: American Chemical Society
Year: 2004
Tongue: English
Weight: 52 KB
Volume: 43
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic0490775

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## Abstract The number of active centers (__C__~P~) and propagation rate constant (__k__~P~) for ethylene polymerization with homogeneous catalyst LCoCl~2~ + MAO and supported catalyst LCoCl~2~/SiO~2~ + Al(__i__‐Bu)~3~, where L is 2,6‐(2,6‐(Me)~2~C~6~H~3~N = CMe)~2~C~5~H~3~N, have been determined u