𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Double α-ketol rearrangement of (1S,2R,4R)-2-acetyl-1-vinyl-2-hydroxy-7,7-dimethylbicyclo[2.2.1]heptane

✍ Scribed by Nikolay S. Vostrikov; Vener Z. Vasikov; Larisa V. Akulova Mansur; S. Miftakhov


Book ID
111730671
Publisher
Royal Society of Chemistry
Year
2006
Tongue
English
Weight
212 KB
Volume
16
Category
Article
ISSN
0959-9436

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


(1R,4R)-1-(Hydroxy­diphenyl­meth­yl)-7,7
✍ Gao, Yu-Xing ;Tang, Guo ;Zhao, Yu-Fen 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 157 KB

The title compound, C 22 H 24 O 2 , has been obtained by a Grignard reaction of (1S,4R)-methyl 7,7-dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylate with phenylmagnesium bromide. Intramolecular hydrogen bonding is observed between the carbonyl group and the hydroxy group.