Double-Oxygen-Atom Transfer in Reactions of CemO2m+ (m=2–6) with C2H2
✍ Scribed by Dr. Xun-Lei Ding; Xiao-Nan Wu; Dr. Yan-Xia Zhao; Jia-Bi Ma; Prof. Sheng-Gui He
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 660 KB
- Volume
- 12
- Category
- Article
- ISSN
- 1439-4235
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Rate constants for the reactions of atomic oxygen ( 0 3 P ) with C&3F, C&IaCl,C@3Br, 1, l-CzHzFz, and I ,2-C&IzFz have been measured at 307' K using a discharge-flow system coupled to a mass spectrometer. The rate constants for these reactions are (in units of 1011cm3mole-1s-1)2.63 &0.38,5.22 =tO0.2
Using the technique of flash photolysis-resonance fluorescence, absolute rate constants have been measured for the reaction H + 0 2 + M 4 HOz + M over a temperature range of 220-360°K. Over this temperature range, the data could be fit to an Arrhenius expression of the following form: The units for
## Abstract Complexes of [Sm~2~(__m__‐ClBA)~6~(phen)~2~] · 2H~2~O and [Sm~2~(__m__‐BrBA)~6~(phen)~2~] · 2H~2~O (__m__‐ClBA = __m__‐chlorobenzoate, __m__‐BrBA = __m__‐bromobenzoate, and phen = 1,10‐phenanthroline) were prepared and characterized by elemental analysis and IR spectra. The thermal deco