A high-resolution analysis of the {ν 2 , ν 3 } and {ν 4 , ν 6 } bands of the two isotopomers of chloryl fluoride F 35 ClO 2 and F 37 ClO 2 has been carried out for the first time using simultaneously infrared spectra recorded around 16 µm and 26 µm with a resolution of ca. 0.003 cm -1 and microwave
Double-Modulation Submillimeter-Wave Spectroscopy of HOC+ in the ν2 Excited Vibrational State
✍ Scribed by T. Amano; A. Maeda
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 102 KB
- Volume
- 203
- Category
- Article
- ISSN
- 0022-2852
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✦ Synopsis
The submillimeter-wave rotational transitions of HOC ϩ in the 2 excited state are first detected using the double-modulation method, and the precise transition frequencies and the much improved molecular constants are obtained. The measurements of the ground state HOC ϩ and DOC ϩ submillimeter-wave lines are extended up to the 840-GHz region. It is found that the higher order centrifugal distortion constant, H, is necessary to fit the observed transition frequencies to the experimental accuracy.
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