Donors and acceptors in tellurium compounds; The problem of doping and self-compensation
β Scribed by J.L. Pautrat; J.M. Francou; N. Magnea; E. Molva; K. Saminadayar
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 960 KB
- Volume
- 72
- Category
- Article
- ISSN
- 0022-0248
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Photoexcitation of a molecular assembly consisting of the donor and acceptor moieties dimethoxynaphthalene and dicyanoethylene rigidly separated by an approximately 15 A long, saturated hydrocarbon bridge results in a charge-separated state with a dipole moment of 77 D and a lifetime of 740 ns in be
The process of intramolecular charge separation was studied in three nearly identical donor-bridge-acceptor compounds (1-3) under jet-cooled conditions. Each consists of a vinylcyanonaphthalene group as a powerful electron acceptor and an anilino derivative as an electron donor, separated by a rigid