On the relation between non-stoichiometry and the formation of donor and acceptor centres in compounds
โ Scribed by F.A. Kroger
- Publisher
- Elsevier Science
- Year
- 1958
- Tongue
- English
- Weight
- 219 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0022-3697
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๐ SIMILAR VOLUMES
## Abstract The tetraketone 3,3,6,6โtetramethylcyclohexaneโ1,2,4,5โtetrone (11) and its congener bicyclo[3.2.2]nonaneโ6,7,8,9โtetrone (17) were synthesized by conventional procedures. The photoreaction of 11 and 17 with tetramethylethylene yields 3,3,4,4,7,7,10,10โoctamethylโ2,5โdioxabicyclo[4.4.0]
The process of intramolecular charge separation was studied in three nearly identical donor-bridge-acceptor compounds (1-3) under jet-cooled conditions. Each consists of a vinylcyanonaphthalene group as a powerful electron acceptor and an anilino derivative as an electron donor, separated by a rigid