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Self-Sorted Assembly in a Mixture of Donor and Acceptor Chromophores

✍ Scribed by Mijanur Rahaman Molla; Anindita Das; Suhrit Ghosh

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
564 KB
Volume
16
Category
Article
ISSN
0947-6539

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Inside Cover: Hydrogen-Bonding Directed
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In a mixed assembly… … of bis-amide-functionalized dialkoxynaphthalene donor and naphthalenediimide acceptor, when there was a mismatch in the relative distance of the amide groups with respect to the two chromophores, self-sorting was observed. On the other hand if the two distances almost matched,

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Photoexcitation of a molecular assembly consisting of the donor and acceptor moieties dimethoxynaphthalene and dicyanoethylene rigidly separated by an approximately 15 A long, saturated hydrocarbon bridge results in a charge-separated state with a dipole moment of 77 D and a lifetime of 740 ns in be