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Donor−Acceptor Interactions and Electron Transfer in Cyano-Bridged Trinuclear Compounds

✍ Scribed by Alborés, Pablo; Rossi, Melina B.; Baraldo, Luis M.; Slep, Leonardo D.

Book ID
126047298
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
260 KB
Volume
45
Category
Article
ISSN
0020-1669

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📜 SIMILAR VOLUMES

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Intramolecular electron transfer rates for ion formation in bridged donor/acceptor systems have been determined using fluorescence lifetime measurements. The data show a weak dependence of the rate on the donor/acceptor distance as well as a dependence on the electronic structure of the spacer. Thes

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Simple dispersion relations are derived which allow for the separation of the contributions of direct electron transfer and hole transfer to the total matrix element between donor and acceptor states in donor-bridge-acceptor charge transfer systems. The proposed relations are based on the calculatio