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Dispersion relations for electron and hole transfer in donor—bridge—acceptor systems

✍ Scribed by Alexei A. Stuchebrukhov

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
591 KB
Volume
225
Category
Article
ISSN
0009-2614

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✦ Synopsis

Simple dispersion relations are derived which allow for the separation of the contributions of direct electron transfer and hole transfer to the total matrix element between donor and acceptor states in donor-bridge-acceptor charge transfer systems. The proposed relations are based on the calculation of the total matrix element for complex tunneling energies and do not assume diagonalixation of the bridge orbitals. A numerical procedure to perform such calculations for proteins and other large electron transfer systems is described.

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