Domino Reactions of 4-Ene-1,2,3-triol Derivatives
✍ Scribed by Prof. Dr. Johann Mulzer; Dipl.-Chem. Stefan Greifenberg; Dr. Jürgen Buschmann; Prof. Dr. Peter Luger
- Publisher
- John Wiley and Sons
- Year
- 1993
- Tongue
- English
- Weight
- 262 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
✦ Synopsis
Crystal structure data for 7:C
📜 SIMILAR VOLUMES
2,4-Dioxopentane-3-thione 1a reacts as an enophile with ethers or allenes as ene counterparts, the formation of the thiophilic adduct is followed by a fast cycloaddition reaction various allyl derivatives affording thiophilic ene adducts as single regioisomers with high (E) stereoselectivity. Using
## Abstract An efficient method to obtain 3E‐alkene‐1,2,5‐triol derivatives with 1,2‐anti stereoselectivity from the corresponding 2Z,4E‐alkadienyl alcohols, which are synthesized by Ni‐catalyzed coupling reaction between lithium 1E‐alkenyl borates and 1‐halo‐1Z‐alken‐3‐ols such as (IX), is describ