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Dominant rovibrational interactions in the local-mode limit

✍ Scribed by F. Michelot; J. Moret-Bailly; A. De Martino

Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
358 KB
Volume
148
Category
Article
ISSN
0009-2614

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✦ Synopsis

It is shown that typical structures computed for the fundamental stretching states of XY3 and XY, molecules can be directly accounted for if local-axis symmetry is introduced. The method is extended to XY6 tops and to other higher excited states.

πŸ“œ SIMILAR VOLUMES

Rovibrational Interactions in the Local-
Rovibrational Interactions in the Local-Mode Limit: The (n000) Stretching Overtone Bands of Spherical Tops
✍ C. Leroy; F. Michelot; V. Boujut πŸ“‚ Article πŸ“… 1995 πŸ› Elsevier Science 🌐 English βš– 612 KB

We present a tensorial formalism adapted to the study of the ( \(n 000\) ) rovibrational stretching states of spherical tops in the local mode limit. A local symmetrized rovibrational basis is built to take explicitly into account the fact that. in these states, the local symmetry is \(C_{3 v}\) rat

Between the local-mode and normal-mode l
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✍ A.C. Scott; P.S. Lomdahl; J.C. Eilbeck πŸ“‚ Article πŸ“… 1985 πŸ› Elsevier Science 🌐 English βš– 639 KB

A simple model system is introduced for the vibrational analysis of polyatomic molecules. Y~US classical system is based on complex mode amplitudes and reduces to either the normal-mode (NM) or the localmode (LM) description in appropriate Limits. Upon analysis without perturbative assumptions, the