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DMC catalyzed epoxide polymerization: Induction period, kinetics, and mechanism

โœ Scribed by Li-Chuan Wu; Ai-Fang Yu; Min Zhang; Bao-Hua Liu; Li-Ban Chen


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
121 KB
Volume
92
Category
Article
ISSN
0021-8995

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Kinetics and mechanism of Rh(III) cataly
โœ P. S. Radhakrishnamurti; S. A. Misra ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 361 KB

## Abstract The kinetics of Rh(III) catalyzed oxidative cleavage of styrene, stilbene, and phenylacetylene by periodate have been investigated in the presence of HClO~4~ in aqueous acetic acid medium. The kinetic orders are completely dependent on the nature of unsaturation. In the cases of styrene