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Distribution of substituents in partially acetylated cellulose

✍ Scribed by Björndal, Håkan ;Lindberg, Bengt ;Rosell, Karl-Gunnar

Publisher
Wiley (John Wiley & Sons)
Year
2007
Weight
232 KB
Volume
36
Category
Article
ISSN
0449-2994

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✦ Synopsis

Abstract

The distribution of substituents in a partially acetylated cellulose (DS 2.4) has been determined. 0‐Acetyl groups were replaced by 0‐methyl groups by using methylsulphinyl sodium and methyl iodide on a product, in which the original free hydroxyl groups had been protected by reaction with methyl vinyl ether. The methylated sugars obtained on acid hydrolysis of this product were converted into alditol acetates and analyzed by GLC‐mass spectrometry.

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