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Distribution of active centers on TiCl4/MgCL2 catalyst for olefin polymerization

✍ Scribed by Zhi-qiang Fan; Lin-Xian Feng; Shi-Lin Yang


Book ID
111697497
Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
527 KB
Volume
34
Category
Article
ISSN
0887-624X

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πŸ“œ SIMILAR VOLUMES


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## Abstract MgCl~2~/TiCl~4~/SiO~2~ catalysts were prepared by treating TiCl~4~/SiO~2~ with MgCl~2~ Β· 2THF (THF: tetrahydrofuran) at different Mg/Ti ratios. The catalysts were analysed by X‐ray, electron spin resonance (ESR), atomic absorption spectrometry to determine the crystal structure, oxidati

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This study focuses on the kinetics of ethylene/propylene (homo/co)polymerization reactions using a high activity TiCl 4 /MgCl 2 /AlEt 3 catalyst. The reactor system is a gas phase reactor equipped with an on-line composition control scheme. As such, important kinetic data such as the instantaneous r