Dissociative electron capture by 1,3-dithiolanes and 1,3-dioxalanes
✍ Scribed by I. I. Furlei; G. V. Leplyanin; V. S. Shmakov
- Book ID
- 112449791
- Publisher
- Springer
- Year
- 1990
- Tongue
- English
- Weight
- 196 KB
- Volume
- 39
- Category
- Article
- ISSN
- 1573-9171
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Irradiation of a solution of 1,3-dithiolane, I-cyanonaphthalene in 02-saturated CH3CN:H20 350 nm furnishes good yields of 1,3-dithiolane-l-oxide. 1,3-Dithiolanes constitute an important functional group in organic chemistry. However, its photochemistry remains underexplored. Eaton et al. 2 observed
## Abstract 1‐Oxo‐1,3‐dithiolane (4) and its __cis__‐ and __trans__‐2‐methyl (5,6), ‐4‐methyl (7,8) and ‐5‐methyl (9,10) derivatives were prepared by oxidizing the corresponding 1,3‐dithiolanes (1–3) with NaIO~4~ in water. The oxides were purified and their isomers separated using thin layer chroma