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Dissociation Constants of Higher Alkyl Phosphate Esters, Phosphonic Acids, Phosphonous Acids, Phosphinic Acids and Carboxylic Acids

โœ Scribed by White, J. R.


Book ID
120470339
Publisher
American Chemical Society
Year
1950
Tongue
English
Weight
252 KB
Volume
72
Category
Article
ISSN
0002-7863

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## Abstract Dialkyl phosphonates add in a 1,2 fashion to the C = N bond in 5,5โ€dimethylโ€3โ€thiozolines **2** to form dialkyl __rac__โ€(4โ€thiazolidinyl)phosphonates **3a** โ€“ **e**. Upon hydrolysis of **3a** __rac__โ€(1โ€aminoโ€2โ€mercaptoโ€2โ€methylpropyl)phosphonic acid (**4a**), the phosphonic acid analog