Dispersed Fluorescence and Computational Study of the 2 × 193 nm Photodissociation of CHBr 3 and CBr 4
✍ Scribed by Petro, Benjamin J.; Tweeten, Eric D.; Quandt, Robert W.
- Book ID
- 120455460
- Publisher
- American Chemical Society
- Year
- 2004
- Tongue
- English
- Weight
- 120 KB
- Volume
- 108
- Category
- Article
- ISSN
- 1089-5639
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Photodissociation of H$ has been studied at 193.3 nm using H atom photofragment-translational speclroscopy with massspectrometric detection. H t HS( v) product branching ratios are reported which are not in quantitative agreement with other recent experimental results. Secondary photodissociation of
Laser photolysis of dicyanoacetylene at 193 nm and at 248 nm, leading to the production of CN, C, and (probably) &N, has been investigated. CN violet bands and Cz Swan bands were observed in absorption. Photolysis at 193 nm produces CN in both the X %+ and in the A 'II, manifolds, the latter -probab