Discriminative Glycosylation of 3-(Aryloxy)propane-1,2-diols by Choice of a Glycosyl Donor.
β Scribed by Hari Babu Mereyala; Sreeman Kumar Mamidyala; Krishna Prasad Chigurupati; Sastri R. Srinivasa
- Book ID
- 101951100
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 90 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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The redwdou of the 2-pyridyl onhster derivative 7 with DIBAL gives excluively the semoduy alco&ol9 in excellent yield. MesyliMioo of 9 followed by reaction with amioes @es the unuwai &alkyL2(lk& pylidms 11 mdl2. Recently a new preparation of N-alkyl-2(1&-pyridones (3) has been reported which involv
## Abstract __N__βBocβprotected serine and threonine esters could be readily added to 2βnitroglycals, affording exclusively Ξ±β and Ξ²βanomers with __galacto__β and __gluco__βconfiguration, respectively. Nitro group reduction to the amino group and also ester cleavage led to compounds **2**, **6**, a