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Glycosylation by sugar 1,2-O-(1-cyanobenzylidene) derivatives: influence of glycosyl-donor structure and promoter

✍ Scribed by Nicolai K. Kochetkov; Vitaly I. Betaneli; Irina A. Kryazhevskikh; Andrey Ya. Ott


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
789 KB
Volume
244
Category
Article
ISSN
0008-6215

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The synthesis of the C-glycoside analogue of the disaccharide Man-(a1 32)Man has been achieved in a highly stereoselective and efficient manner employing an approach which closely parallels O-glycoside synthesis. The key step included the samarium diiodide reduction of mannosyl pyridylsulfone 18 in