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ChemInform Abstract: Samarium Diiodide Promoted C-Glycosylation: An Application to the Stereospecific Synthesis of α-1,2-C-Mannobioside and Its Derivatives.

✍ Scribed by Olivier Jarreton; Troels Skrydstrup; Juan-Felix Espinosa; Jesus Jimenez-Barbero; Jean-Marie Beau

Publisher
John Wiley and Sons
Year
2010
Weight
38 KB
Volume
30
Category
Article
ISSN
0931-7597

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Samarium Diiodide Promoted C-Glycosylati
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The synthesis of the C-glycoside analogue of the disaccharide Man-(a1 32)Man has been achieved in a highly stereoselective and efficient manner employing an approach which closely parallels O-glycoside synthesis. The key step included the samarium diiodide reduction of mannosyl pyridylsulfone 18 in

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