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Discrete AdEreactions of dicobalthexacarbonyl complexes of conjugated enynes with participation of C-electrophiles and C-nucleophiles

✍ Scribed by G. S. Mikaelyan; A. S. Gybin; W. A. Smith

Book ID
112443610
Publisher
Springer
Year
1984
Tongue
English
Weight
137 KB
Volume
33
Category
Article
ISSN
1573-9171

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πŸ“œ SIMILAR VOLUMES

Discrete introduction of the electrophil
Discrete introduction of the electrophile and nucleophile in AdE -reactions of dicobalt hexacarbonyl complexes of conjugated enynes.
✍ A.A. Schegolev; W.A. Smit; Y.B. Kalyan; M.Z. Krimer; R. Caple πŸ“‚ Article πŸ“… 1982 πŸ› Elsevier Science 🌐 French βš– 193 KB

The dicobalt hexacarbonyl complex of the enyne isopropenylacetylene (1) is effective in permitting stepwise AdE reactions to the double bond of 1 via stabilization of the intermediate carbenium ion. We have been interested for some time in stepwise AdE reactions of alkenes where the electrophile and