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Two-step AdEreaction of dicobalthexacarbonyl complexes of conjugated enynes with independent variation in the nature of the electrophile and nucleophile

✍ Scribed by A. A. Shchegolev; W. A. Smit; G. S. Mikaelyan; A. S. Gybin; Yu. V. Kal'yan; M. Z. Krimer; R. Caple

Book ID: 112442711
Publisher: Springer
Year: 1984
Tongue: English
Weight: 751 KB
Volume: 33
Category: Article
ISSN: 1573-9171
DOI: 10.1007/bf00948853

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The dicobalt hexacarbonyl complex of the enyne isopropenylacetylene (1) is effective in permitting stepwise AdE reactions to the double bond of 1 via stabilization of the intermediate carbenium ion. We have been interested for some time in stepwise AdE reactions of alkenes where the electrophile and