Enolate-Phosphane Ligands Providing a To
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Bernard Demerseman; LoΓ―c Toupet
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Article
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2006
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John Wiley and Sons
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English
β 203 KB
π 2 views
## Abstract The deprotonation under basic conditions of the ketoβphosphane ligand in complexes {Ru(Cp)[Ξ·^1^β__P__βPh~2~PCH~2~C(=O)__t__Bu](PPh~3~)(L)}[PF~6~] (L = CO or PMe~3~) that arise from the addition of L to {Ru(Cp)[Ξ·^2^β__P__,__O__βPh~2~PCH~2~C(__t__Bu)=O](PPh~3~)}[PF~6~] generates {Ru^+^(Cp