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Direct α-arylation of ketones: The reaction of cyclic ketone enolates with diphenyliodonium triflate

✍ Scribed by John H. Ryan; Peter J. Stang

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
191 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis

Diphenyliodonium triflate la reacts with the lithium enolates of cyclic ketones 2 (ring size = 5 -8), in the presence of stoichiometric quantiites of copper cyanide, to afford the corresponding tx-phenylated ketones 3 or ct,~'diphenylated ketones 4.

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