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Reaction of Allylzinc Reagents and Zinc Enolates of Ketones with α-Amidoalkylphenyl Sulfones.

✍ Scribed by Marino Petrini; Roberto Profeta; Paolo Righi

Publisher
John Wiley and Sons
Year
2010
Weight
38 KB
Volume
33
Category
Article
ISSN
0931-7597

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📜 SIMILAR VOLUMES

Thioalkylation of enolates, II. – α-Thio
Thioalkylation of enolates, II. – α-Thioalkylation of Zinc Enolates to α,α-Disubstituted Ketones
✍ Groth, Ulrich ;Huhn, Thomas ;Richter, Norbert 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 640 KB

## Abstract An α‐alkylation of the 2‐methylcycloalkanones 1 and 4 at the higher substituted carbon can be achieved by thioalkylation of the corresponding zinc enolates with the α‐chlorosulfides 3. The desulfurization can be carried out with either Raney nickel or lithium in diethylamine for compoun