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Direct Synthesis of Pseudo-Disaccharides by Rearrangement of Unsaturated Disaccharides

✍ Scribed by Alan James Pearce; Matthieu Sollogoub; Jean-Maurice Mallet; Pierre Sinaÿ

Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
520 KB
Volume
1999
Category
Article
ISSN
1434-193X

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✦ Synopsis

The series of unsaturated disaccharides 10-14 undergo (triisobutylaluminium) to afford (1Ǟ4) and (1Ǟ6) etherlinked pseudo-disaccharides 2-9. stereoselective reductive rearrangement with TIBAL to afford substituted cyclohexane derivatives with retention

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