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ChemInform Abstract: One-Step Synthesis of Disaccharide Mimetics via Tandem Rearrangement of Unsaturated Disaccharides.

โœ Scribed by Alan James Pearce; Jean-Maurice Mallet; Pierre Sinay

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
31
Category
Article
ISSN
0931-7597

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โœ A. L. J. BYERLEY; A. M. KENWRIGHT; P. G. STEEL ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 31 KB ๐Ÿ‘ 1 views

Synthesis of C-Disaccharides via Glucal Dimerization. -Treatment of 3-O-acetyl glucals with acetyl perchlorate gives the corresponding dimeric C-disaccharides with high diastereoselectivity at the new C-C bond. In the case of (II), formation of side products ( III) and (IV) is confirmed as well. A d