ChemInform Abstract: Synthesis of C-Disaccharides via Glucal Dimerization.
β Scribed by A. L. J. BYERLEY; A. M. KENWRIGHT; P. G. STEEL
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Synthesis of C-Disaccharides via Glucal Dimerization. -Treatment of 3-O-acetyl glucals with acetyl perchlorate gives the corresponding dimeric C-disaccharides with high diastereoselectivity at the new C-C bond. In the case of (II), formation of side products ( III) and (IV) is confirmed as well. A different reaction course is observed for substrates (IX) and (XI). -(BYERLEY, A.
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