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Determination of unsaturated glycosaminoglycan disaccharides by spectrophotometry on thin-layer chromatographic plates

✍ Scribed by Anna-Marja Säämänen; Markku Tammi


Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
446 KB
Volume
140
Category
Article
ISSN
0003-2697

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✦ Synopsis


Chondroitin sulfate isomers and hyaluronate, digested with chondroitinase AC II and separated as unsaturated disaccharides by thin-layer chromatography on cellulose, were quantitated with scanning spectrophotometry using reflectance measurement at 232 nm. The sensitivity of the assay was increased by one order of magnitude as compared to previous modifications of the disaccharide analysis on cellulose. The method allowed quantitation of 0.2-20 micrograms of glycosaminoglycan uronic acid. Since the elution of the disaccharides from the plate could be omitted, the speed and reproducibility of the assay was enhanced.