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Direct substitution of aromatic ethers by lithium amides. A new aromatic amination reaction

โœ Scribed by ten Hoeve, Wolter; Kruse, Chris G.; Luteyn, Jan M.; Thiecke, Janet R. G.; Wynberg, Hans


Book ID
121205307
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
608 KB
Volume
58
Category
Article
ISSN
0022-3263

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A new selective type of aromatic substit
โœ F. Minisci; G.P. Gardini; R. Galli; F. Bertini ๐Ÿ“‚ Article ๐Ÿ“… 1970 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 119 KB

The prevalent nucleophilic character of the alkyl radicals' readily permits thehomolyticalkylation of protonated heteroaromatic bases2, due to the contribution of polar forms in the transition state: The oxygen atom of ethersand alcohols as well as the nitrogen of amides and amines, attached to the