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A new, highly selective, type of aromatic substitution. Homolytic amination of phenolic ethers.

✍ Scribed by Francesco Minisci; Remo Galli

Publisher
Elsevier Science
Year
1965
Tongue
French
Weight
151 KB
Volume
6
Category
Article
ISSN
0040-4039

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A new selective type of aromatic substit
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The prevalent nucleophilic character of the alkyl radicals' readily permits thehomolyticalkylation of protonated heteroaromatic bases2, due to the contribution of polar forms in the transition state: The oxygen atom of ethersand alcohols as well as the nitrogen of amides and amines, attached to the

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## Abstract Summary: Poly(arylene ether amine)s were synthesized by a nucleophilic aromatic substitution polycondensation of bis[4‐fluoro‐3‐(trifluoromethyl)phenyl]amine with several bisphenols. Even though the monomer has an electron‐donating diphenylamine moiety, which normally deactivates a nucl