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Direct resolution of novel tetrahedral metal clusters on a cellulose tris-(3,5-dimethylphenylcarbamate) chiral stationary phase by high-performance liquid chromatography

✍ Scribed by Xinyi Zhu; Yingchun Cai; Weiqiang Zhang; Liren Chen; Yongmin Li

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
417 KB
Volume
26
Category
Article
ISSN
1615-9306

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✦ Synopsis

Abstract

Direct optical resolution of five novel tetrahedral heterometal cluster enantiomers has been achieved for the first time on a cellulose tris‐(3,5‐dimethylphenylcarbamate) chiral stationary phase, using hexane as the mobile phase with various alcohols as modifiers. UV detection was carried out at 254 nm. The influence of the mobile phase composition on enantioselectivity is discussed and optimum resolution has been achieved. The effect of structural variation of the solutes on their enantioseparation has also been investigated.

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