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Direct rate measurements showing negative temperature dependence for reaction of atomic oxygen with cis-2-butene and tetramethylethylene

✍ Scribed by Davis, D. D.

Book ID
121309078
Publisher
American Institute of Physics
Year
1973
Tongue
English
Weight
730 KB
Volume
59
Category
Article
ISSN
0021-9606

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The kinetics of the reactions of ground state oxygen atoms with 1-pentene, 1-hexene, cis-2pentene, and trans-2-pentene was investigated in the temperature range 200 to 370 K. In this range the temperature dependences of the rate constants can be represented by k ϭ AЈ T n exp(Ϫ E a Ј/RT) with AЈ ϭ (1