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Rate constants of reactions of oxygen atoms with n-octane and cis-and trans-butenes-2

โœ Scribed by L. I. Avramenko; R. V. Kolesnikova; G. I. Savinova

Book ID
112435468
Publisher
Springer
Year
1967
Tongue
English
Weight
463 KB
Volume
16
Category
Article
ISSN
1573-9171

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## Abstract The kinetics of the reactions of ground state oxygen atoms with __trans__โ€2โ€butene, __cis__โ€2โ€butene, 2โ€methylpropene, 2โ€methylโ€2โ€butene, and 2,3โ€dimethylโ€2โ€butene was investigated in the temperature range 200 to 370K. In this range, the rate constants are (in units 10^โˆ’11^ cm^3^ s^โˆ’1^)

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The kinetics of the reactions of ground state oxygen atoms with 1-pentene, 1-hexene, cis-2pentene, and trans-2-pentene was investigated in the temperature range 200 to 370 K. In this range the temperature dependences of the rate constants can be represented by k ฯญ Aะˆ T n exp(ฯช E a ะˆ/RT) with Aะˆ ฯญ (1