Direct Methylation of Bis(benzimidazole-2-N-phenylcarbothioamidato)copper(II)
✍ Scribed by A. P. Ranskii; A. G. Panasyuk
- Book ID
- 110330697
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2002
- Tongue
- English
- Weight
- 47 KB
- Volume
- 28
- Category
- Article
- ISSN
- 1070-3284
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 295 K Mean (C-C) = 0.004 A R factor = 0.043 wR factor = 0.105 Data-to-parameter ratio = 16.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.005 A Ê Disorder in main residue R factor = 0.038 wR factor = 0.106 Data-to-parameter ratio = 13.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, [Cu(C 15 H 14 NO) 2 ], adopts a stepped conformation and displays a square-planar trans-[CuN 2 O 2 ] coordination geometry. The asymmetric unit contains two independent half molecules and each Cu atom is located on a center of symmetry. For one molecule, the CuÐN and CuÐO bond di
The title compound, [Cu(C 9 H 13 N 2 O 2 S) 2 ], is a centrosymmetric neutral complex with the Cu II atom showing slightly distorted square-planar CuN 4 geometry. The crystal packing is consolidated by intramolecular N-HÁ Á ÁO and intermolecular C-HÁ Á Á interactions.