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Direct Measurements of Deuterium Kinetic Isotope Effects in Anionic, Gas-Phase Substitution and Elimination Reactions

โœ Scribed by Gronert, Scott; Fagin, Adelaide E.; Wong, Lawrence

Book ID
120494145
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
37 KB
Volume
129
Category
Article
ISSN
0002-7863

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The kinetics of the gas phase intramolecular elimination of isobutene from 2-d1-triisobutylaluminum and the deuterium isotope effect in reactions involving cyclic transition states
โœ Kurt W. Egger ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 654 KB

The intramolecular elimination of isobutene from 2-d,-triisobutylaluminum has been studied in the gas phase for temperatures ranging between 102.4 and 184.6'C. The reaction is apparently homogeneous and obeys the first order rate law, yielding the following Arrhenius relationship: log kelim (sec-')