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Deuterium Kinetic Isotope Effects in Microsolvated Gas-Phase E2 Reactions: Methanol and Ethanol as Solvents

โœ Scribed by Nicole Eyet; Stephanie M. Villano; Veronica M. Bierbaum

Book ID
108158452
Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
232 KB
Volume
19
Category
Article
ISSN
1044-0305

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The kinetics of the gas phase intramolec
The kinetics of the gas phase intramolecular elimination of isobutene from 2-d1-triisobutylaluminum and the deuterium isotope effect in reactions involving cyclic transition states
โœ Kurt W. Egger ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 654 KB

The intramolecular elimination of isobutene from 2-d,-triisobutylaluminum has been studied in the gas phase for temperatures ranging between 102.4 and 184.6'C. The reaction is apparently homogeneous and obeys the first order rate law, yielding the following Arrhenius relationship: log kelim (sec-')