𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Direct Involvement of the Acetato Ligand in the Reductive Elimination Step of Rhodium-Catalyzed Methanol Carbonylation

✍ Scribed by Lassauque, Nicolas; Davin, Thomas; Nguyen, Duc Hanh; Adcock, Romain J.; Coppel, Yannick; Le Berre, Carole; Serp, Philippe; Maron, Laurent; Kalck, Philippe

Book ID
126211157
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
644 KB
Volume
51
Category
Article
ISSN
0020-1669

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

On the rhodium catalyzed formation of ac
On the rhodium catalyzed formation of acetic acid from methyl formate β€” comparison with the rhodium catalyzed formation of acetic acid by direct carbonylation of methanol
✍ G. Bub; H.-U. HΓΆg πŸ“‚ Article πŸ“… 1995 πŸ› Elsevier Science 🌐 English βš– 662 KB

In presence of the homogenous Rh/Cr/I catalyst system methyl formate can be isomerized to acetic acid under CO-pressure with high conversion rates and excellent selectivity. This catalyst system has never been applied before for this reaction.