Phosphinoureas: Cooperative Ligands in Rhodium-Catalyzed Hydroformylation? On the Possibility of a Ligand-Assisted Reductive Elimination of the Aldehyde
β Scribed by Meeuwissen, Jurjen; Sandee, Albertus J.; de Bruin, Bas; Siegler, Maxime A.; Spek, Anthony L.; Reek, Joost N. H.
- Book ID
- 120008298
- Publisher
- American Chemical Society
- Year
- 2010
- Tongue
- English
- Weight
- 970 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0276-7333
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π SIMILAR VOLUMES
Various dithioureas bearing an aromatic ring on their terminal nitrogen atoms have been synthesized. These have been tested in the asymmetric reduction of ketones as catalyzed by a rhodium complex. The influence of electron-withdrawing and electron-donating substituents on the aromatic rings on the
The biphasic rhodium catalyzed hydroformylation of water insoluble olefins in the presence of chemically modified β€-cyclodextrins has been investigated. The influence of various parameters, such as the nature of the β€-cyclodextrin, the concentrations of phosphine or cyclodextrin and the temperature