Square-Planar Carbonylchlororhodium(I) C
✍
Sylvain Burger; Bruno Therrien; Georg Süss-Fink
📂
Article
📅
2005
🏛
John Wiley and Sons
🌐
German
⚖ 113 KB
## Abstract The rhodium(I) complexes __trans__‐[Rh(diphos)(CO)Cl] **7** (diphos=pbpb), **8** (diphos=nbpb), and **9** (diphos=cbpb) were synthesized (__Scheme 4__) and used as catalysts for the carbonylation of MeOH to AcOH (__Scheme 1__). The __trans__ coordination imposed by the rigid C‐spacer fr