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New Diphosphine Ligands Containing Ethyleneglycol and Amino Alcohol Spacers for the Rhodium-Catalyzed Carbonylation of Methanol

✍ Scribed by Christophe M. Thomas; Roger Mafua; Bruno Therrien; Eduard Rusanov; Helen Stœckli-Evans; Georg Süss-Fink


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
251 KB
Volume
8
Category
Article
ISSN
0947-6539

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Square-Planar Carbonylchlororhodium(I) C
✍ Sylvain Burger; Bruno Therrien; Georg Süss-Fink 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 German ⚖ 113 KB

## Abstract The rhodium(I) complexes __trans__‐[Rh(diphos)(CO)Cl] **7** (diphos=pbpb), **8** (diphos=nbpb), and **9** (diphos=cbpb) were synthesized (__Scheme 4__) and used as catalysts for the carbonylation of MeOH to AcOH (__Scheme 1__). The __trans__ coordination imposed by the rigid C‐spacer fr