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Direct Experimental Observation of CS2OH

โœ Scribed by Giulia de Petris; Marzio Rosi; Anna Troiani

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
124 KB
Volume
7
Category
Article
ISSN
1439-4235

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Reaction of OH radicals with CS2
Reaction of OH radicals with CS2
โœ V.P. Bulatov; S.G. Cheskis; A.A. Iogansen; P.V. Kulakov; O.M. Sarkisov; E. Hassi ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 351 KB

The title reaction was studied by the direct time-resolved laser-induced lluorescence method at room temperature. The rate constants for the forward and reverse reactions were measured to be (1.92 0.5) x lo-" cm3 molecule-' s-l and (7.4&2.5)x IO4 s-', respectively. The rate constant forthe reaction

OCS formation in the reaction of OH with
OCS formation in the reaction of OH with CS2
โœ B.M.R. Jones; J.P. Burrows; R.A. Cox; S.A. Penkett ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 370 KB

A steady-state system involvmg phato~s~ of HONO asa source of OH was used to ~~e5trgate the reaction of OH wtth CS2 at 1 atm and 295 Ii. In the presence of 02 (240 Torr) a rapid reaction of OH with CSz occurs giving OCS. At lower Oz concentrafionq 0C.S formation ceases. fn au the overall rate consta