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Direct Observation of OH Reductive Elimination from IrIII Complexes

โœ Scribed by Ofer Blum; Prof. David Milstein


Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
402 KB
Volume
34
Category
Article
ISSN
0044-8249

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Anions of 1,3-dicarbonyl compounds are some of the most common ligands in transition-metal chemistry. [1, 2] They typically bind in an h 2 -O,O fashion, [3] have delocalized charge, and donate electron density more weakly to a metal center than alkyls or alkoxides. They are usually supporting ligand