Generation of Reactivity from Typically
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Joanna P. Wolkowski; John F. Hartwig
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Article
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2002
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John Wiley and Sons
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English
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Anions of 1,3-dicarbonyl compounds are some of the most common ligands in transition-metal chemistry. [1, 2] They typically bind in an h 2 -O,O fashion, [3] have delocalized charge, and donate electron density more weakly to a metal center than alkyls or alkoxides. They are usually supporting ligand