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Direct Detection of 1,1-Diphenylgermene in Solution and Absolute Rate Constants for Germene Trapping Reactions

✍ Scribed by Toltl, Nicholas P.; Leigh, William J.

Book ID: 126823250
Publisher: American Chemical Society
Year: 1998
Tongue: English
Weight: 105 KB
Volume: 120
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja973756f

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## Abstract Absolute rate constants are reported for the addition of the 1‐[(__tert__‐butoxy)carbonyl]ethyl (= 2‐(1,1‐dimethylethoxy)‐1‐methyl‐2‐oxoethyl) radical ^.^CHMeCO~2~(__t‐__Bu) to several cyclic and monosubstituted alkenes in MeCN as obtained by time‐resolved electron paramagnetic resonanc