Absolute rate constants for the bimolecular reaction of radical pairs in solution. Benzyl and pentyl radicals
✍ Scribed by Burkhart, Richard D.
- Book ID
- 126905355
- Publisher
- American Chemical Society
- Year
- 1968
- Tongue
- English
- Weight
- 602 KB
- Volume
- 90
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract Cyano‐substituted methyl radicals (cyanomethyl–hand 2‐cyano‐2‐propyl radicals) and __syn__‐and __anti__‐1‐cyano‐allyl radicals were generated, and their recombination kinetics in solution were investigated between −50 and +50°C by time‐resolved electron‐spin‐resonance spectroscopy. The
## Abstract The rate constant for the bimolecular combination of benzyl radicals in cyclohexane and toluene is determined as a function of temperature. Further, it is studied in cyclohexane–toluene mixtures of different compositions. In the entire range covered, 9.8 × 10^8^ ⩽ 2__k__~t~ ⩽ 9.0 × 10^9
## Abstract Rate constants for the self‐reaction of __tert__butyl radicals in six __n__alkanes are determined as functions of temperature by kinetic electron‐spin resonance spectroscopy and from rates of product formation. They are well described by a Smoluchowski–Stokes–Einstein treatment includin