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Direct Catalytic Asymmetric Aldol-Tishchenko Reaction.

โœ Scribed by Vijay Gnanadesikan; Yoshihiro Horiuchi; Takashi Ohshima; Masakatsu Shibasaki

Publisher
John Wiley and Sons
Year
2004
Weight
31 KB
Volume
35
Category
Article
ISSN
0931-7597

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๐Ÿ“œ SIMILAR VOLUMES

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## Abstract The development of a direct catalytic asymmetric aldolโ€“Tishchenko reaction and the nature of its catalyst are described. An aldolโ€“Tishchenko reaction of various propiophenone derivatives with aromatic aldehydes was promoted by [LaLi~3~(binol)~3~] (LLB), and reactivity and enantioselecti

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In the synthesis of complex molecular targets, the ability to control the stereoselectivity of the aldol reaction has raised this process to a level of prominence shared by few reactions. In most cases, however, the stoichiometric transformation of the active methylene partner into its enolate or an