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The Direct Catalytic Asymmetric Aldol Reaction

✍ Scribed by Benito Alcaide; Pedro Almendros

Publisher: John Wiley and Sons
Year: 2002
Tongue: English
Weight: 174 KB
Volume: 2002
Category: Article
ISSN: 1434-193X
DOI: 10.1002/1099-0690(200205)2002:10<1595::aid-ejoc1595>3.0.co;2-m

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✦ Synopsis

In the synthesis of complex molecular targets, the ability to control the stereoselectivity of the aldol reaction has raised this process to a level of prominence shared by few reactions. In most cases, however, the stoichiometric transformation of the active methylene partner into its enolate or an enol derivative is a drawback. Only recently have several reports ad-

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