Dipotassium sodium hexacyanocobalt(III)
✍ Scribed by Ilyukhin, Andrey B. ;Kotov, Vitalii Yu.
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 211 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The title compound, K 2 [Co II (H 2 O) 6 ] 2 [V 10 O 28 ]Á4H 2 O, was obtained by reacting CoCl 2 with KVO 3 and it was found to crystallize in the triclinic system in space group P1. The VÁ Á ÁV distances are in the range 3.050 (1)±3.291 (2) A Ê ; the four types of VÐO bond length are in the ranges
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.011 A Ê R factor = 0.056 wR factor = 0.154 Data-to-parameter ratio = 12.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
## Abstract (Octaethylporphyrinato)cobalt(II), OEPCo (1), reacts with sodium cyanide and undergoes simultaneous oxidation with air oxygen to form sodium dicyano(octaethylporphyrinato)‐cobalt(III), Na[OEPCo(CN)~2~] (2), which is converted into μ‐cyano(octaethylporphyrinato)‐cobalt(III), [OEPCoCN]~__